A non-traditional method of characterization of petroleum mixtures in terms
of selected real components is described which stems from the results of t
he mixture analysis and from some of distillation curves - best of all, EFV
curve. On the basis of mathematical modelling of the process of obtaining
the EFV curve, it is possible to find the composition of a substitute mixtu
re consisting of a lower number of real components of the original mixture.
This substitute mixture exhibits very similar vapour-liquid equilibrium be
haviour as the original multicomponent mixture, which makes it possible to
simplify the calculation of, e.g., a rectification column. At the same time
, the need disappears of estimating the thermodynamic data of single mixtur
e components on the basis of empirical relations subject usually to conside
rable errors so as it is with the commonly employed method of pseudocompone
nts.