Softening of the interactions between surfactant bilayers in a lamellar phase due to the presence of a polymer

The compressibility modulus of a lamellar phase containing a neutral polyme r guest molecule was measured directly using a surface force apparatus. The system studied consisted of sodium dodecyl sulphate (SDS), pentanol, water and polyethylene glycol (PEG) (M-w = 22600 g/mol). The lamellar phase was induced from a micellar phase in situ via a confinement induced isotropic t o lamellar phase transition. This avoided problems resulting from the visco sity and turbidity normally characteristic of these lamellar phase samples. Increasing the amount of PEG resulted in a marked decrease in the layer co mpressibility modulus (B) over bar indicating a decrease in the repulsive f orces between the lamellae. The origin of such a phenomenon is discussed in terms of different mechanisms including depletion interactions, bridging i nteractions and modification of the electrostatic interaction between the l amellae by the polymer.