Flow injection analysis of hydrogen peroxide in disinfectants

Citation
D. Harms et al., Flow injection analysis of hydrogen peroxide in disinfectants, FRESEN J AN, 364(1-2), 1999, pp. 184-188
Citations number
17
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY
ISSN journal
09370633 → ACNP
Volume
364
Issue
1-2
Year of publication
1999
Pages
184 - 188
Database
ISI
SICI code
0937-0633(199905)364:1-2<184:FIAOHP>2.0.ZU;2-W
Abstract
A flow injection analysis (FIA) method for the automated determination of h ydrogen peroxide in the presence of even stronger oxidants is presented bas ed on the immediate formation of a colored adduct between hydrogen peroxide and a dinuclear iron(III) complex.-A reagent stream with the complex and a carrier stream into which the sample is injected are combined in a low dea d volume mixing tee. A reaction coil provides for a reaction time of 7 s, a fter which detection is performed using UV/vis spectroscopy at 575 nm. Majo r advantages of the method are the simple experimental setup and the high s electivity even towards stronger oxidants. Real samples have been investiga ted and the method has been validated using independent techniques includin g microplate spectrophotometry and HPLC.