Variational total energies from phi- and Psi-derivable theories

Citation
Co. Almbladh et al., Variational total energies from phi- and Psi-derivable theories, INT J MOD B, 13(5-6), 1999, pp. 535-541
Citations number
15
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INTERNATIONAL JOURNAL OF MODERN PHYSICS B
ISSN journal
02179792 → ACNP
Volume
13
Issue
5-6
Year of publication
1999
Pages
535 - 541
Database
ISI
SICI code
0217-9792(19990310)13:5-6<535:VTEFPA>2.0.ZU;2-5
Abstract
Starting from many-body perturbation theory we have constructed a new varia tional expression for the total energy of many-electron systems. This expre ssion is a functional of two independent variables, the one-electron Green function and the screened Coulomb interaction. The new functional as well a s a much older variational expression by Luttinger and Ward (LW) are tested on the interacting electron gas. Both functionals yield extraordinary accu rate total energies although the new functional requires a much cruder inpu t and is therefore easier to apply to more realistic systems.