Instrumented tensile and falling weight impact response of injection-molded alpha- and beta-phase polypropylene homopolymers with various melt flow indices

Citation
J. Karger-kocsis et al., Instrumented tensile and falling weight impact response of injection-molded alpha- and beta-phase polypropylene homopolymers with various melt flow indices, J APPL POLY, 73(7), 1999, pp. 1205-1214
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
73
Issue
7
Year of publication
1999
Pages
1205 - 1214
Database
ISI
SICI code
0021-8995(19990815)73:7<1205:ITAFWI>2.0.ZU;2-A
Abstract
In this study the instrumented tensile (ITI) and falling weight impact (IFW I) behavior of injection-molded alpha- and beta-phase polypropylene (PP) ho mopolymers were compared at ambient temperature in a broad melt flow index (MFI = 0.7-13 dg/min) range. It was found that the toughness of beta-PP is superior to the alpha-PP: the difference between them increased with decrea sing MFI or increasing molecular weight (MW). As expected, the injection mo lding induced skin layer thickness increased with increasing MW. Effects of the skin-core morphology were deduced indirectly by considering the result s achieved on specimens molded at low and high injection speeds (upsilon(in j) = 6 and 150 mm/s), respectively. It was found that the effect of the ski n-core structure is markedly stronger under uniaxial in-plane (i.e., ITI) t han in biaxial out-of-plane type loading (i.e., IFWI). (C) 1999 John Wiley & Sons, Inc.