Synthesis and characterization of outer coordination sphere complexes: [LH+](2)[SnCl62-], [LH+](2)[Me4Sn2Cl62-] and [LH+][Ph2SnCl3-](LH+ = protonated2-methoxy-1-[(4-chlorophenylimino)methyl]naphthalene). Crystal structure of 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalenium trichlorodiphenylstannate(IV), [LH+][Ph2SnCl3-], derived from diphenyltin dichloride and 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalene

Authors
Yeap, GY Ng, AC Teoh, SG Teo, SB Declercq, JP
Citation
Gy. Yeap et al., Synthesis and characterization of outer coordination sphere complexes: [LH+](2)[SnCl62-], [LH+](2)[Me4Sn2Cl62-] and [LH+][Ph2SnCl3-](LH+ = protonated2-methoxy-1-[(4-chlorophenylimino)methyl]naphthalene). Crystal structure of 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalenium trichlorodiphenylstannate(IV), [LH+][Ph2SnCl3-], derived from diphenyltin dichloride and 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalene, J COORD CH, 48(1), 1999, pp. 63-72
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
48
Issue
1
Year of publication
1999
Pages
63 - 72
Database
ISI
SICI code
0095-8972(1999)48:1<63:SACOOC>2.0.ZU;2-E
Abstract
The reactions of SnCl4, Me2SnCl2 and Ph2SnCl2 with the Schiff base (L) 2-me thoxy-1-[(4-chlorophenylimino)methyl]naphthalene result in the formation of tin(IV) anionic complexes. Ph2SnCl2 reacts with the Schiff base in dichlor omethane to form the complex salt [LH+][Ph2SnCl3-] (LH+ = protonated L). X- ray structural analysis has been carried out on a single crystal of [LH+][P h2SnCl3-]. The reactions of SnCl4 and Me2SnCl2 with the Schiff base form th e complexes [LH+](2)[SnCl62-] and [LH+](2)[Me4Sn2Cl62-], respectively. All complex salts were characterized by elemental analysis and spectroscopic me thods (IR and H-1 NMR).