Relaxation rate distributions for supercooled liquids

Citation
T. Franosch et W. Gotze, Relaxation rate distributions for supercooled liquids, J PHYS CH B, 103(20), 1999, pp. 4011-4017
Citations number
36
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
103
Issue
20
Year of publication
1999
Pages
4011 - 4017
Database
ISI
SICI code
1520-6106(19990520)103:20<4011:RRDFSL>2.0.ZU;2-D
Abstract
The mode-coupling theory for the evolution of glassy dynamics in simple liq uids yields correlation functions that, outside the transient regime, can b e written as a superposition of relaxators with a broad distribution of rel axation rates. The known asymptotic laws for the dynamics near an ideal gla ss transition imply corresponding laws for the rate distribution. We calcul ate the rate distributions for a hard-sphere liquid and compare them to the leading and next-to-leading asymptotic formulas.