Nonexponential primary relaxation in supercooled salol

Citation
G. Diezemann et K. Nelson, Nonexponential primary relaxation in supercooled salol, J PHYS CH B, 103(20), 1999, pp. 4089-4096
Citations number
40
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
103
Issue
20
Year of publication
1999
Pages
4089 - 4096
Database
ISI
SICI code
1520-6106(19990520)103:20<4089:NPRISS>2.0.ZU;2-O
Abstract
The nonexponential relaxation in supercooled salol near the calorimetric gl ass transition temperature is analyzed in terms of a free-energy model for the primary relaxation in glass-forming liquids. In comparing the results f rom impulsive stimulated thermal scattering and dielectric data, we estimat e the mean angle of reorientational fluctuations in the supercooled liquid for a temperature range located between the glass transition temperature an d the critical temperature of mode coupling analyses on salol. The mean reo rientational jump angle is estimated to increase smoothly from about 20 deg rees to 50 degrees with increasing temperature in the considered range. The se values are in qualitative accord to what was found in other supercooled liquids in a similar range before.