Rd. Gordon et El. Cussler, Adsorption of oxygen on YBa2Cu3O7-x and (Bi,Pb)(2)Sr2Ca2Cu3Ox superconducting adsorbents, LANGMUIR, 15(11), 1999, pp. 3950-3955
The adsorption of oxygen on a high-temperature superconductor is not inhibi
ted by superconducting forces. The equilibrium adsorption isotherms of oxyg
en and nitrogen on superconducting YBa2Cu3O7-x and (Bi,Pb)(2)Sr2Ca2Cu3Ox at
17 K are equivalent. Moreover, the equilibrium adsorption of oxygen on sup
erconducting YBa2Cu3O7-x and (Bi,Pb)(2)Sr2Ca2Cu3Ox and on nonsuperconductin
g SiO2 at 77 K are equivalent. These results agree with theoretical argumen
ts that predict the magnetic repulsion of oxygen from a superconductor to b
e significant over a distance of angstroms. At these distances, the magneti
c forces are constrained by the superconductor's penetration depth and no M
eissner effect is observed, contrary to the results of past reports.