Microcalorimetric measurements of small absorption coefficients have been p
erformed on thin GaN-AlGaN quantum wells grown by Reactive Molecular Beam E
pitaxy on Al2O3 substrates. In addition to strong absorption at the energy
of the GaN buffer and at the energy of the thick AlGaN barrier layers, we c
ould also readily detect transitions associated to the quantum well. These
measurements which pave the way to a precise determination of the gap misma
tch between the well and the barrier layers are combined with self consiste
nt excitonic and envelope function calculations in the context of a model f
or the band line-ups which includes the piezoelectric effect. (C) 1999 Else
vier Science S.A. All rights reserved.