Concentrations of halide ions of river waters in the Kusatsu-Shirane v
olcano area, Gunma, were measured by ion chromatography. The decreasin
g order of concentration among halide ions at various sampling locatio
ns is in general; chloride ion>fluoride ion>bromide ion>iodide ion. A
strong correlation was observed between the concentrations of the chlo
ride and bromide ions. High halide ion concentrations were observed in
river waters indicating that the volcanic activity of Mt. Kusatsu-Shi
rane is the major source of halide ions in river waters of the area. M
easurements of halide ion concentrations along the downward streams of
selected rivers revealed that concentration ratios among halide ions
were not varied substantially in the absence of any circumstantial cha
nge. The amounts of halide ions transported from the Kusatsu-Shirane v
olcano area by rivers per year were estimated to be 1.4 x 10(7) mol fo
r the fluoride ion, 3.8 x 10(8) mol for the chloride ion, 4.1 x 10(5)
mol for the bromide ion and 1.0 x 10(5) mol for the iodide ion.