Static compression of the hydrous magnesium silicate phase D to 30 GPa at room temperature

Authors
Citation
Dj. Frost et Y. Fei, Static compression of the hydrous magnesium silicate phase D to 30 GPa at room temperature, PHYS CHEM M, 26(5), 1999, pp. 415-418
Citations number
25
Categorie Soggetti
Earth Sciences
Journal title
PHYSICS AND CHEMISTRY OF MINERALS
ISSN journal
03421791 → ACNP
Volume
26
Issue
5
Year of publication
1999
Pages
415 - 418
Database
ISI
SICI code
0342-1791(199905)26:5<415:SCOTHM>2.0.ZU;2-C
Abstract
Phase D is a dense hydrous magnesium silicate (ideal formula MgSi2H2O6) whi ch contains silicon cations exclusively in octahedral coordination. Measure ments of the unit cell parameters of phase D were made to pressures of 30 G Pa using a diamond anvil cell and employing synchrotron X-ray diffraction. A neon pressure medium was used. Using a third order Birch-Murnaghan equati on of state the isothermal bulk modulus of phase D was determined as 166(+/ -3) GPa with K' equal to 4.1(+/-0.3). The compression of phase D is anisotr opic with the c-axis twice as compressible as the a-axis. Above 20 GPa, how ever, the c/a ratio becomes pressure independent.