The dominant mechanisms of electron generation and loss during different ph
ases of spark discharge are considered. The focus is on spark formation in
long non-uniform-field air gaps through leader and streamer processes. The
streamer development in dry air and the effects of humidity, temperature an
d density on the properties of a long positive streamer in air are discusse
d. The ionization kinetics in the leader channel in long air gaps is descri
bed. The ionization mechanisms which lead to the re-breakdown within a post
-arc air channel and to the streamer breakdown in undisturbed air and in Ar
are presented.