A. Hansel et al., Proton-transfer-reaction mass spectrometry (PTR-MS): on-line monitoring ofvolatile organic compounds at volume mixing ratios of a few pptv, PLASMA SOUR, 8(2), 1999, pp. 332-336
A system for on-line measurements of trace compounds in air with concentrat
ions as low as a few pptv has been developed on the basis of proton transfe
r reactions. The sensitivity of this system is demonstrated by means of cal
ibration data of benzene and data on the diurnal variation of C9-alkylbenze
ne and its C-13-isotope in ambient air. First on-line data on the concentra
tions of volatile organic compounds obtained during plane flights are prese
nted.