Regioselective halogenation of primary alcohol groups of cyclodextrins with halomethylenemorpholinium halides Vilsmeier-Haack reagents

Authors
Chmurski, K Defaye, J
Citation
K. Chmurski et J. Defaye, Regioselective halogenation of primary alcohol groups of cyclodextrins with halomethylenemorpholinium halides Vilsmeier-Haack reagents, POL J CHEM, 73(6), 1999, pp. 967-971
Citations number
13
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
73
Issue
6
Year of publication
1999
Pages
967 - 971
Database
ISI
SICI code
0137-5083(199906)73:6<967:RHOPAG>2.0.ZU;2-M
Abstract
Per(6-bromo-6-deoxy)cyclomalto-hexaose, -heptaose, and -octaose and the cor responding per(6-chloro-6-deoxy) derivatives were prepared in high yield by reaction of bromomethylenemorpholinium bromide or chloromethylenemorpholin ium chloride, respectively, with cyclomaltohexaose, cyclomaltoheptaose and cyclomaltooctaose in dimethylformamide.