St. Tan et al., Effect of interfacial modification on metal fiber filled polypropylene composites and property balance, POLYM COMP, 20(3), 1999, pp. 406-412
Mechanical properties and electrical conductivity of discontinuous stainles
s steel fiber (SSF) filled polypropylene (PP) composites were considered as
candidates for shielding electromagnetic interference (EMI) applications.
In order to improve the unsatisfied impact resistance, surface treatments o
f SSF and modified PP were introduced. By means of a microdroplet pull-out
test, polypropylene grafted maleic anhydride copolymer (PP-g-MAH) was found
to be able to enhance the poor interfacial adhesion between fiber and matr
ix. On this basis, PP-g-MAH was used to prepare conventional composites, an
d the macromechanical measurements showed evidence that PP-g-MAH helped inc
rease both flexural and impact strength of the composites. However, the goo
d affinity of PP-g-MAH for SSF reduced composite conductivity accordingly.
Finally, blends of PP and PP-g-MAH proved to be a solution for the problem,
i.e., the impact strength was increased significantly while acceptable ele
ctrical resistivity was maintained.