A SYNTHESIS OF 6-MYOPOROL

Authors
HO TL CHEIN RJ
Citation
Tl. Ho et Rj. Chein, A SYNTHESIS OF 6-MYOPOROL, Journal of natural products, 60(5), 1997, pp. 493-494
Citations number
4
Categorie Soggetti
Chemistry,"Plant Sciences","Pharmacology & Pharmacy","Chemistry Medicinal
Journal title
Journal of natural products → ACNP
ISSN journal
01633864
Volume
60
Issue
5
Year of publication
1997
Pages
493 - 494
Database
ISI
SICI code
0163-3864(1997)60:5<493:ASO6>2.0.ZU;2-G
Abstract
An approach to (+/-)-6-myoporol (1) featured stereocontrol by equilibr ation of 2,6-disubstituted cyclohexanones to mainly the cis isomer. Th e synthesis was completed by reaction of a lactone intermediate with 3 -lithiofuran, Mitsunobu reaction, and hydrolysis.