The influence of CO2 on the phase stability of Bi-2212

Citation
P. Majewski et al., The influence of CO2 on the phase stability of Bi-2212, SUPERCOND S, 12(5), 1999, pp. 249-254
Citations number
12
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SUPERCONDUCTOR SCIENCE & TECHNOLOGY
ISSN journal
09532048 → ACNP
Volume
12
Issue
5
Year of publication
1999
Pages
249 - 254
Database
ISI
SICI code
0953-2048(199905)12:5<249:TIOCOT>2.0.ZU;2-2
Abstract
The influence of CO2 on the stability of the compound Bi2.18Sr2CaCu2O8+d (2 212) has been determined as a function of temperature and time. 2212 has be en found to be unstable at CO2 partial pressures above about 10(-2) bar. Si ngle-phase 2212 ceramics decompose at such CO2 partial pressures forming li quid + CuO + (Sr, Ca)CO3. Solubility of carbon in 2212 was not detected.