Synthesis and characterization of a new mono-molybdenated metallo-ligand [Mo{HB(3,5-Me2C3HN2)(3)} (NO)Cl(OC6H4PPh2-p)]

Authors
Topaloglu, I McCleverty, JA
Citation
I. Topaloglu et Ja. Mccleverty, Synthesis and characterization of a new mono-molybdenated metallo-ligand [Mo{HB(3,5-Me2C3HN2)(3)} (NO)Cl(OC6H4PPh2-p)], SYN REAC IN, 29(6), 1999, pp. 1101-1109
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
6
Year of publication
1999
Pages
1101 - 1109
Database
ISI
SICI code
0094-5714(1999)29:6<1101:SACOAN>2.0.ZU;2-5
Abstract
The "metallo-ligands" can be considered effectively as a modified triphenyl phosphine ligand, and used to generate novel transtion metal complexes in w hich electron-transfer and magnetism is embedded within the stable ligand f ramework. A new mono-molybdenated metallo-ligand was synthesized and charac terized by NMR (H-1 and P-31-{H-1}), IR and mass spectroscopy techniques as a starting material in the search for designing novel bimetallic complexes exhibiting optoelectronic properties and development of non-linear optical materials that possess commercial device applications.