Synthesis and structure of [NbCl3(NPPh(2)Fc)(2)]: The first example of a complex containing a redox-functionalised phosphaneiminato ligand

Authors
Siemeling, U Stammler, A Stammler, HG Kuhnert, O
Citation
U. Siemeling et al., Synthesis and structure of [NbCl3(NPPh(2)Fc)(2)]: The first example of a complex containing a redox-functionalised phosphaneiminato ligand, Z ANORG A C, 625(6), 1999, pp. 845-847
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
6
Year of publication
1999
Pages
845 - 847
Database
ISI
SICI code
0044-2313(199906)625:6<845:SASO[T>2.0.ZU;2-G
Abstract
Reaction of Me(3)SiNPPh(2)Fc (Fc = ferrocenyl) with niobium pentachloride a ffords [NbCl3(NPPh(2)Fc)(2)], whose redox-functionalised phosphaneiminato l igands exhibit remarkably different bend angles at nitrogen according to a crystal structure analysis.