Synthesis of dimethoxyethane and tetrahydrofuran complexes of rare-earth nitrates - Solid state structure of Pr(NO3)(3)(thf)(4)

Authors
Niemeyer, M
Citation
M. Niemeyer, Synthesis of dimethoxyethane and tetrahydrofuran complexes of rare-earth nitrates - Solid state structure of Pr(NO3)(3)(thf)(4), Z ANORG A C, 625(6), 1999, pp. 848-850
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
6
Year of publication
1999
Pages
848 - 850
Database
ISI
SICI code
0044-2313(199906)625:6<848:SODATC>2.0.ZU;2-D
Abstract
The solvated rare-earth nitrates Ln(NO3)(3)(thf)(n) (Ln=Pr, n=4 (1): Ln=Ho (2), Yb (3), n=3 and Ln(NO3)(3)(dme)(2); Ln = Pr (4), Ho (5)) were obtained from Ln(NO3)(3)(H2O)(x) and HC(OCH3)(3). Pale green thermally labile cryst als of 1 were characterized by X-ray crystallography. The praseodymium atom s in two independent monomeric molecules show capped trigonal prismatic and pentagonal bipyramidal coordination, respectively.