On thermodynamic characteristics of In-I system compounds

Citation
Va. Titov et al., On thermodynamic characteristics of In-I system compounds, Z ANORG A C, 625(6), 1999, pp. 1013-1018
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
6
Year of publication
1999
Pages
1013 - 1018
Database
ISI
SICI code
0044-2313(199906)625:6<1013:OTCOIS>2.0.ZU;2-X
Abstract
The temperature dependences of the total vapour pressure for solid and liqu id InI2 and liquid InI3 were measured by the static method with a membran-g auge manometer. The heat capacities above phases and solid InI3 were also o btained. The partial pressures In2I6, InI3, InI, In2I4, I-2, I were calcula ted. Absolute entropies and enthalpies of formation InI2 (crII), InI2 (1), In2I4 (g), InI3 (1), InI3 (g), In2I6 (g) were obtained. We used the least s quare method to obtain the mutual consistent sets of data on thermodynamic characteristics of indium iodides in condensed and gaseous phases. The resu lt of this work is the set of standard formation enthalpies and absolute en tropies of the In-I system compounds.