Spectroscopic and thermal properties of chromyl acetate and trifluoroacetate

Authors
Brandan, SA Ben Altabef, A Varetti, EL
Citation
Sa. Brandan et al., Spectroscopic and thermal properties of chromyl acetate and trifluoroacetate, AN AS QUIM, 87(1-2), 1999, pp. 89-96
Citations number
10
Categorie Soggetti
Chemistry
Journal title
ANALES DE LA ASOCIACION QUIMICA ARGENTINA
ISSN journal
03650375 → ACNP
Volume
87
Issue
1-2
Year of publication
1999
Pages
89 - 96
Database
ISI
SICI code
0365-0375(199901/04)87:1-2<89:SATPOC>2.0.ZU;2-C
Abstract
Chromyl acetate and trifluoroacetate were prepared as polymeric solids, wit h infrared spectra showing features due to monodentate and bidentate carbox ylate groups. The UV-visible spectra of both substances are also reported. The thermolysis products indicate an oxydative process of Cr(VI) acting upo n the organic ligands.