Initial stages of cobalt-disilicide formation in mesotaxy

Citation
Gr. Carlow et M. Zinke-allmang, Initial stages of cobalt-disilicide formation in mesotaxy, CAN J CHEM, 76(11), 1998, pp. 1737-1745
Citations number
32
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
76
Issue
11
Year of publication
1998
Pages
1737 - 1745
Database
ISI
SICI code
0008-4042(199811)76:11<1737:ISOCFI>2.0.ZU;2-U
Abstract
We present results on the formation of buried silicide layers at ion implan tation doses in the range of 1-60% of the critical dose for formation of a uniform layer We emphasize observations for the low-dose range of 1-5% wher e the precipitate density is quite dilute. The Co redistribution during pos t-implant annealing is measured using Rutherford backscattering techniques and secondary ion mass spectrometry. Experimental observations during posti mplantation annealing at 1000 degrees C involves (i) a contraction of the C o depth profile for all doses, (ii) shifting of the peak of the profile tow ards the hulk, and (iii) formation of a secondary Co peak near the surface. The secondary peak is only present in samples implanted to greater than 3% of the critical dose. The interpretation of the shift of the main peak and the occurrence of the secondary peak requires a model exceeding the standa rd ripening model used previously to describe mesotaxy. We suggest that mor e recent ripening-based concepts allow for a full description of these obse rvations with a minimum of parameters, particularly not requiring interacti on with the complex defect profiles formed initially during implantation. E ssential for this model is a proper inclusion of precipitate-precipitate in teractions and the role of diffusion screening.