A multicomponent mass transfer model based on the Stefan-Maxwell formalism
is developed to predict membrane distillation performance in separating aze
otropic mixtures. The developed model accounts for all coupling interaction
s between the diffusing species as well as for temperature and concentratio
n polarization effects. The model is validated with previously published ex
perimental data of propionic acid/water azeotropic mixture. The model predi
cts the effect of the process relevant parameters very well. (C) 1999 Publi
shed by Elsevier Science S.A. All rights reserved.