INITIAL-STAGES OF THE FORMATION OF THE STRUCTURE OF METAL-HYDROXIDES

Citation
Nt. Denisov et Af. Shestakov, INITIAL-STAGES OF THE FORMATION OF THE STRUCTURE OF METAL-HYDROXIDES, Russian chemical bulletin, 45(12), 1996, pp. 2703-2708
Citations number
20
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
45
Issue
12
Year of publication
1996
Pages
2703 - 2708
Database
ISI
SICI code
1066-5285(1996)45:12<2703:IOTFOT>2.0.ZU;2-T
Abstract
Based on the data for the initial stage of aging of metal hydroxides t hat exhibit nitrogen fixation properties and the exact solution of the model kinetic problem for the association of aqua and hydroxo complex es, the regularities of the formation of the structure of primary amor phous particles of metal hydroxides have been revealed. The primary pa rticles consist of chain hydroxo polymers that contain ca. 10 units an d are chemically bound to each other by mu(3)-OH bridging groups in si tes at chaotically arranged intersections.