The paper summarizes results achieved in the Institute of Radio Engineering
and Electronics in the field of investigation and fabrication of novel fib
er-optic structures for evanescent-wave chemical sensing. Several approache
s for increasing the evanescent-wave sensitivity of multimode silica optica
l fibers to gaseous and liquid chemicals are shown. These approaches make u
se of the decrease of the core diameter in sectorial and capillary sectoria
l fibers, modification of trajectories of optical rays in the cores of inve
rted-graded-index fibers, tailoring of the refractive index of porous layer
s applied on silica cores, an output mode filter preventing the detection o
f rays propagating at low axial angles or fibers bent in single or multiple
turns.