ANODIC PERFLUOROALKYLATION OF THE ENOL ACETATE OF ETHYL ACETOACETATE

Authors
KISLYI VP KURYKIN MA GRINBERG VA KAGRAMANOV ND SEMENOV VV
Citation
Vp. Kislyi et al., ANODIC PERFLUOROALKYLATION OF THE ENOL ACETATE OF ETHYL ACETOACETATE, Russian chemical bulletin, 45(12), 1996, pp. 2800-2803
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
12
Year of publication
1996
Pages
2800 - 2803
Database
ISI
SICI code
1066-5285(1996)45:12<2800:APOTEA>2.0.ZU;2-T
Abstract
Electrochemical perfluoroalkylation of the enol acetate of ethyl aceto acetate was studied in the conditions of the Kolbe reaction. The yield s of alkylation products depend on the competing adsorption of the eno l acetate, the solvent, and perfluorocarboxylates on the surface of a platinum electrode.