Na. Chernyavskaya et Ma. Kurykin, SYNTHESIS OF METHYLVINYLPOLYFLUOROALKOXYSILANES BY PHOTOINITIATED RADICAL REACTION OF DIALKOXY(METHYL)VINYLSILANES WITH PERFLUORO-4-METHYLPENT-2-ENE, Russian chemical bulletin, 45(12), 1996, pp. 2827-2829
A new method was elaborated for the synthesis of vinylsilanes with pol
yfluoroalkoxy substituents at the silicon atom using the photoinitiate
d radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-me
thylpent-2-ene in the presence of di-tert-butyl peroxide at room tempe
rature.