SYNTHESIS OF METHYLVINYLPOLYFLUOROALKOXYSILANES BY PHOTOINITIATED RADICAL REACTION OF DIALKOXY(METHYL)VINYLSILANES WITH PERFLUORO-4-METHYLPENT-2-ENE

Citation
Na. Chernyavskaya et Ma. Kurykin, SYNTHESIS OF METHYLVINYLPOLYFLUOROALKOXYSILANES BY PHOTOINITIATED RADICAL REACTION OF DIALKOXY(METHYL)VINYLSILANES WITH PERFLUORO-4-METHYLPENT-2-ENE, Russian chemical bulletin, 45(12), 1996, pp. 2827-2829
Citations number
18
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
45
Issue
12
Year of publication
1996
Pages
2827 - 2829
Database
ISI
SICI code
1066-5285(1996)45:12<2827:SOMBPR>2.0.ZU;2-W
Abstract
A new method was elaborated for the synthesis of vinylsilanes with pol yfluoroalkoxy substituents at the silicon atom using the photoinitiate d radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-me thylpent-2-ene in the presence of di-tert-butyl peroxide at room tempe rature.