POLYFERROORGANOSILOXANES AS CATALYSTS OF OXIDATION PROCESSES

Authors
KULIKOVA VS LEVITSKY MM BUCHACHENKO AL
Citation
Vs. Kulikova et al., POLYFERROORGANOSILOXANES AS CATALYSTS OF OXIDATION PROCESSES, Russian chemical bulletin, 45(12), 1996, pp. 2870-2872
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
12
Year of publication
1996
Pages
2870 - 2872
Database
ISI
SICI code
1066-5285(1996)45:12<2870:PACOOP>2.0.ZU;2-A
Abstract
Polyferroorganosiloxanes were studied as catalysts for homogeneous oxi dation of alkanes by hydrogen peroxide under mild conditions. In the o xidation of cyclohexane the catalysts are characterized by high effici ency (conversion of hydrogen peroxide is 25%) and stability (up to 80 cycles per g-at. Fe). The main product of the oxidation in the presenc e of 2,4,6-tri-tert-butylphenol is cyclohexanol (up to 35% per H2O2).