Radical double helicates of silver imino nitroxides, [Ag-2(pyrd-im2)(2)](PF6)(2)center dot 2CH(3)OH and [Ag-2(bpy-im2)(2)](PF6)(2)center dot CH3OH

Authors
Oshio, H Yaginuma, T Ito, T
Citation
H. Oshio et al., Radical double helicates of silver imino nitroxides, [Ag-2(pyrd-im2)(2)](PF6)(2)center dot 2CH(3)OH and [Ag-2(bpy-im2)(2)](PF6)(2)center dot CH3OH, INORG CHEM, 38(11), 1999, pp. 2750
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
11
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990531)38:11<2750:RDHOSI>2.0.ZU;2-O
Abstract
Oligo-pyridyl type diradicals of imino nitroxide are assembled by silver io ns. In the crystals, four imino nitroxides are arranged to form double stra nded helicates. A substantial antiferromagnetic interaction between radical centers through a pyridazyl group was observed.