A new carbonate bridged dinuclear zinc complex with tripodal amine ligands

Authors
Dietrich, J Heinemann, FW Schrodt, A Schindler, S
Citation
J. Dietrich et al., A new carbonate bridged dinuclear zinc complex with tripodal amine ligands, INORG CHIM, 288(2), 1999, pp. 206-209
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
288
Issue
2
Year of publication
1999
Pages
206 - 209
Database
ISI
SICI code
0020-1693(19990530)288:2<206:ANCBDZ>2.0.ZU;2-9
Abstract
A zinc complex with the tripodal ligand bis[2-(2-pyridyl)ethyl]-(2-pyridyl) methylamine (pmap) reacts with carbon dioxide to form a new dinuclear carbo nate bridged zinc complex, [mu-CO3 {Zn(pmap)}(2)](ClO4)(2). This complex wa s structurally characterized and shows a binding mode for carbonate, which so far has not been observed for zinc carbonate complexes. (C) 1999 Elsevie r Science S.A. All rights reserved.