Experimental and modelling study of methyl oleate pyrolysis between 500 and 650 degrees C

Citation
D. Archambault et F. Billaud, Experimental and modelling study of methyl oleate pyrolysis between 500 and 650 degrees C, J CHIM PHYS, 96(5), 1999, pp. 778-796
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
96
Issue
5
Year of publication
1999
Pages
778 - 796
Database
ISI
SICI code
Abstract
This paper describes an experimental and modelling study of methyl oleate p yrolysis in a tubular flow reactor at atmospheric pressure. The reaction te mperatures ranged from 500 to 650 degrees C. The residence times were 230, 350, 500 and 600 ms. The proposed radical mechanism describes qualitatively all experimental obs erved species. This mechanism displays a satisfactory agreement between exp erimental and simulated values of molar fractions of pyrolysis reaction pro ducts.