Polarization studies on zinc in hydrochloric acid solution containing someorganic solvents

Authors
Citation
Ak. Mohamed, Polarization studies on zinc in hydrochloric acid solution containing someorganic solvents, J CHIM PHYS, 96(5), 1999, pp. 830-837
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
96
Issue
5
Year of publication
1999
Pages
830 - 837
Database
ISI
SICI code
Abstract
The corrosion behaviour of zinc metal in some organic solvents was tested e lectrochemically using galvanometric polarization measurements, The results showed that the studied organic solvents act as mixed type inhibitors, The inhibition was assumed to occur via physical adsorption of the inhibitor m olecules fitting a Temkin's isotherm, The inhibition eficiency of the solve nts increase in the order: glycerol>ethylene glycol>DMSO>dioxane. This orde r is not affected by the variation in temperature in the range 35-55 degree s C. The increase in temperature was found to increase the corrosion in abs ence and in presence of inhibitors. Some thermodynamic parameters for adsor ption were also computed and discussed.