Kl. Yeung et al., Palladium composite membranes by electroless plating technique - Relationships between plating kinetics, film microstructure and membrane performance, J MEMBR SCI, 159(1-2), 1999, pp. 107-122
Thin supported palladium membranes were prepared using electroless plating
technique. The intrinsic plating kinetics were determined for hydrazine-bas
ed palladium plating baths. Mathematical models were developed to predict f
ilm thickness and plating rate as a function of plating parameters (i.e., r
eactant concentrations, temperature and time). Analyses of film surface mic
rostructure indicate that grain structure is dependent on both plating chem
istry and plating rate. The evolution of film morphology during electroless
plating was also investigated. Hydrogen permeation study demonstrated that
film structure has a significant influence on the permeation performance o
f the palladium membrane. (C) 1999 Elsevier Science B.V. All rights reserve
d.