Treatment of electronic stopping via kinetic theory and the orbital local p
lasma approximation is extended (from free-standing ordered slabs) to inclu
de bulk crystalline targets, and hence probe their electron momentum distri
bution. Sensitive computational issues, important for comparison with exper
imental data, are addressed. A primary result is unambiguous first-principl
es prediction of large gas-solid and film-solid differences in Li stopping.
Previous predictions had involved semi-empirical determination of mean exc
itation energies. Additionally, a stopping anisotropy that is separate from
and much smaller than familiar channelling and related to the familiar Com
pton-profile anisotropy is treated, apparently for the first time. Example
calculations for hexagonal Li and graphite are given.