Synthesis and characterisation of 8-aminoquinoline complexes of platinum(II) and palladium(II). Kinetics of dimethyl sulphoxide entry into the coordination sphere
M. Ray et al., Synthesis and characterisation of 8-aminoquinoline complexes of platinum(II) and palladium(II). Kinetics of dimethyl sulphoxide entry into the coordination sphere, J INDIAN CH, 76(3), 1999, pp. 121-124
The synthesis and characterisation of 8-aminoquinoline (8-AMQ) complexes of
platinum(II) and palladium(II) have been reported. Kinetic study of dimeth
yl sulfoxide (DMSO) entry into the coordination sphere of Pt(8-AMQ)Cl-2 and
Pd(8-AMQ)Cl-2 has been undertaken through spectrophotometric measurements
showing the replacement of one Cl- from the complexes. H-1 nmr studies supp
ort the S-bonding to the metal centre in the DMSO substituted species.