Synthesis and characterisation of 8-aminoquinoline complexes of platinum(II) and palladium(II). Kinetics of dimethyl sulphoxide entry into the coordination sphere

Authors
Ray, M Bhattacharya, S Banerjee, P
Citation
M. Ray et al., Synthesis and characterisation of 8-aminoquinoline complexes of platinum(II) and palladium(II). Kinetics of dimethyl sulphoxide entry into the coordination sphere, J INDIAN CH, 76(3), 1999, pp. 121-124
Citations number
7
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF THE INDIAN CHEMICAL SOCIETY
ISSN journal
00194522 → ACNP
Volume
76
Issue
3
Year of publication
1999
Pages
121 - 124
Database
ISI
SICI code
0019-4522(199903)76:3<121:SACO8C>2.0.ZU;2-B
Abstract
The synthesis and characterisation of 8-aminoquinoline (8-AMQ) complexes of platinum(II) and palladium(II) have been reported. Kinetic study of dimeth yl sulfoxide (DMSO) entry into the coordination sphere of Pt(8-AMQ)Cl-2 and Pd(8-AMQ)Cl-2 has been undertaken through spectrophotometric measurements showing the replacement of one Cl- from the complexes. H-1 nmr studies supp ort the S-bonding to the metal centre in the DMSO substituted species.