Reversible P-C bond formation for saturated alpha-aminophosphine ligands in solution: stabilization by coordination to Cu(I)

Authors
Andrieu, J Dietz, J Poli, R Richard, P
Citation
J. Andrieu et al., Reversible P-C bond formation for saturated alpha-aminophosphine ligands in solution: stabilization by coordination to Cu(I), NEW J CHEM, 23(6), 1999, pp. 581-583
Citations number
14
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
6
Year of publication
1999
Pages
581 - 583
Database
ISI
SICI code
1144-0546(199906)23:6<581:RPBFFS>2.0.ZU;2-8
Abstract
The saturated alpha-aminophosphine ligands containing a secondary amine fun ction Ph2PCH(R')NHR " establish a solution equilibrium with Ph2PH and R'CH= NR " and are stabilized by electron-withdrawing substituents R' and R " and by coordination of the phosphorous donor to Cu(I).