P. Brydon et al., Bond-valence analysis of charge distribution in the spin ladders of [M2Cu2O3](m)[CuO2](n)-type cuprates with m=n=1, PHIL MAG L, 79(6), 1999, pp. 383-387
The bond-valence-sum method is used to calculate the hole distribution in t
he spin ladders of [M2Cu2O3](m)[CuO2](n)-type cuprates with m = n = 1 (wher
e M are divalent or trivalent cations). It is shown that the appearance of
superconductivity in this system is related to hole transfer from chain pla
nes to the spin-ladder plane. The role of the valency and size of the M ato
ms is discussed in detail.