We present an extensive study of the AB(2) polymeric Hubbard chains with ex
perimental motivation in inorganic and organic compounds. In the half-fille
d strong-coupling limit, these systems can be mapped onto a quantum antifer
romagnetic spin-1/2 AB(2) Heisenberg model that presents a zero-temperature
quantum phase transition to a ferrimagnetic ground state. We derive the sp
in-wave modes with the same correct ferromagnetic dispersion relation calcu
lated through two different techniques. We also build an Euclidean integral
formulation in the coherent state representation which naturally gives ris
e to Wess-Zumino terms of topological origin. The low-energy infrared behav
ior of the AB(2) chains is properly described through a renormalization gro
up analysis by the semiclassical fixed point of a one-dimensional quantum n
onrelativistic nonlinear sigma model with critical dynamical exponent z = 2
. Their low-temperature behavior is shown to be the same of a quantum ferro
magnetic spin-1/2 Heisenberg chain, as evidenced by the temperature depende
nce of the correlation length, susceptibility, and specific heat. On the ot
her hand, a quantum critical fixed point is also found, with the same zero-
temperature critical behavior of a classical Heisenberg system in D = d + z
= 3 dimensions. Its low-temperature critical properties are related to the
latter through the crossover exponent phi = z nu(3), where nu(3) is the co
rrelation length exponent of the D = 3 classical Heisenberg model. Sufficie
ntly strong quantum critical fluctuations destroy the ordered ground state
of the quantum z = 2 nonlinear sigma model (but not that of the quantum AB(
2) Heisenberg spin systems, in agreement with a theorem by Lieb), giving ri
se to a quantum disordered phase at zero temperature. These results are sup
ported by a connection between the quantum AB(2) Heisenberg and generalized
quantum rotor models. [S0163-1839(99)14671-6].