Self-assembled indium linear chains on the Si(lll) surface are found to exh
ibit instability of the metallic phase and 1D charge density wave (CDW). Th
e room-temperature metallic phase of these chains undergoes a temperature-i
nduced, reversible transition into a semiconducting phase. The 1D CDW along
the chains is observed directly in real space by scanning tunneling micros
copy at low temperature. The Fermi contours of the metallic phase measured
by angle-resolved photoemission exhibit a perfect nesting predicting precis
ely the CDW periodicity. [S0031-9007(99)09330-8].