Citation
Zb. Zhang et al., Synthesis of fluorine-containing block copolymers via ATRP 2. Synthesis and characterization of semifluorinated di- and triblock copolymers, POLYMER, 40(19), 1999, pp. 5439-5444
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER
ISSN journal
00323861
→ ACNP
Volume
40
Issue
19
Year of publication
1999
Pages
5439 - 5444
Database
ISI
SICI code
0032-3861(199909)40:19<5439:SOFBCV>2.0.ZU;2-4
Abstract
A series of semifluorinated fluorocarbon/hydrocarbon di- and triblock copol
ymers were prepared by atom transfer radical polymerization (ATRP). The mon
o- and difunctional macroinitiators, which were obtained from bulk ATRP of
styrene, butyl acrylate and methyl acrylate, initiated solution ATRP of 2-
[(perfluorononenyl)oxy]ethyl methacrylate and ethylene glycol mono-methacry
late mono-perfluorooctanoate, respectively. The formation of the block copo
lymer was confirmed with size exclusion chromatography and H-1 NMR spectrum
. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.