Study of the polymerization of solid vinyl monomers using differential scanning calorimetry

Authors
Ali, AAM Al-Sagheer, F Elsabee, MZ
Citation
Aam. Ali et al., Study of the polymerization of solid vinyl monomers using differential scanning calorimetry, POLYM TEST, 18(4), 1999, pp. 313-319
Citations number
7
Categorie Soggetti
Material Science & Engineering
Journal title
POLYMER TESTING
ISSN journal
01429418 → ACNP
Volume
18
Issue
4
Year of publication
1999
Pages
313 - 319
Database
ISI
SICI code
0142-9418(1999)18:4<313:SOTPOS>2.0.ZU;2-H
Abstract
Two vinyl monomers with a heterocyclic group have been prepared. The solid state polymerization of the two monomers was investigated by DSC. The activ ation energy as well as the order of reaction were calculated using differe nt free radical initiators. It has been shown that the nature of the monome r and the initiator affect the behavior of polymerization. H-1 NMR spectros copy was used to confirm the polymerization. (C) 1999 Elsevier Science Ltd. All rights reserved.