This paper presents a brief overview of improved Liquid membrane (LM) separ
ation techniques, including modified bulk, supported and emulsion liquid me
mbranes as well as hollow fibre contained liquid membranes, electrostatic p
seudo liquid membranes (ESPLIM) reverse micelle and recently developed hybr
id (HLM) and other LM configurations. The discussion also includes design o
f ion specific carriers, analytical importance, aspects of stability and mo
delling of LMs and their applications in the separation/removal of metal ca
tions from a range of diverse matrices. In general, an attempt has been mad
e to review the literature published from 1990 to 1997 in order to focus on
the present status of different liquid membrane configurations. The LM stu
dies dealing with separation and removal of organic compounds and gases are
not included in this article owing to limitations of space.