Phthalimidesulfenyl chloride 12: Generation and trapping of para-monothioquinones

Authors
Cantini, B Capozzi, G Menichetti, S Nativi, C
Citation
B. Cantini et al., Phthalimidesulfenyl chloride 12: Generation and trapping of para-monothioquinones, SYNTHESIS-S, (6), 1999, pp. 1046-1050
Citations number
20
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
6
Year of publication
1999
Pages
1046 - 1050
Database
ISI
SICI code
0039-7881(199906):6<1046:PC1GAT>2.0.ZU;2-#
Abstract
The reaction of phthalimidesulfenyl chloride 7 with o,o'-disubstituted phen ols affords p-hydroxythiophthalimides which are the precursors of the corre sponding p-thioquinones. The latter species are generated under mild condit ions and efficiently trapped with 1,3-dienes.