A diffuse reflectance laser flash photolysis study of solid beta-cyclodextrin inclusion complexes of xanthone and acetoveratrone

Citation
M. Mir et F. Wilkinson, A diffuse reflectance laser flash photolysis study of solid beta-cyclodextrin inclusion complexes of xanthone and acetoveratrone, AN QUIM-INT, 94(4-5), 1998, pp. 206-210
Citations number
29
Categorie Soggetti
Chemistry
Journal title
ANALES DE QUIMICA-INTERNATIONAL EDITION
ISSN journal
11302283 → ACNP
Volume
94
Issue
4-5
Year of publication
1998
Pages
206 - 210
Database
ISI
SICI code
1130-2283(1998)94:4-5<206:ADRLFP>2.0.ZU;2-L
Abstract
The photochemistry of solid beta-cyclodextrin (beta-CD) inclusion complexes of xanthone and acetoveratrone has been studied by steady-state emission s pectroscopy and diffuse reflectance laser flash photolysis (DRLFP). The for mation of beta-CD inclusion complexes of acetoveratrone in aqueous solution has been established by means of steady-state emission spectroscopy. The a nalysis of the guest triplet decay in the solid beta-CD complexes using the Albery model confirms that such a model can provide a better understanding of the inclusion effect in solid cyclodextrin complexes and therefore can help with the understanding of the weak interactions in supramolecular chem istry.