Selective etching of GaAs over AlGaAs and InGaP was examined in different p
lasma chemistries (BCl3/SF6, BCl3/NF3, IBr, ICI, BI3, and BBr3) in a high d
ensity plasma reactor. The normal etch stop reactions involving formation o
f involatile AlF3, InF3, or InCl3 are found to be less effective under high
density conditions because of the higher ion-assisted etch product desorpt
ion efficiency. Addition of SF6 to BCl3, produces higher selectivities than
NF3 as an additive, while IBr, ICI and BBr3 are essentially non-selective
for both heterostructure systems. Selective etching of InGaP over GaAs is a
chieved using the BI3 chemistry. (C) 1999 Elsevier Science B.V. All rights
reserved.