Experimental study of the effect of bubbles, drops and particles on the product distribution for a mixing sensitive, parallel-consecutive reaction system

For stirred multiphase reactors the effect of a dispersed (gas, liquid or s olid) phase on the product distribution for a mixing sensitive reaction was tested. Turbulence modification due to the presence of dispersed-phase par ticles has been reported frequently in literature, but the extent of the ef fect in a stirred multiphase reactor was not clear. In this work the well-k nown mixing sensitive diazo-coupling reaction system was selected to invest igate the influence of the changes in the turbulent kinetic energy spectrum on the product distribution. This reaction system was found to be suitable to study the influence of a dispersed (gas, liquid or solid) phase. The En gulfment model could describe the single-phase experiments and describes re asonably well the multiphase experiments when the effective dispersion prop erties are implemented. For the liquid-liquid dispersions effects of de-loc alization of the reaction zone were encountered, due to Naphthol extraction by the dispersed phase. The Engulfment model was extended to incorporate m ass transfer and the first experimental and simulation results are promisin g. Additional, experimental and theoretical, research studying the combined effects of the mass transfer rate and the mixing rate for the liquid-liqui d dispersions is highly desired. (C) 1999 Elsevier Science Ltd. All rights reserved.