This paper deals with the micromixing phenomenon occurring when ultrasonic
waves propagate in a reacting medium. Parallel competing reactions A + B --
> R and C + vB --> S were employed to quantify the micromixing. We have use
d a 20 kHz horn in a batch reactor to investigate the influence of the acou
stic power. Various vessels have been tested in order to study the influenc
e of the reacting volume (100-500-3750 ml). The dissipated power, and not t
he power per unit mass was found to be the determining variable. Then a cla
ssic impeller was compared to the ultrasound device in aqueous media. Value
s of characteristic micromixing time around 0.005 s have been obtained for
both the mixing processes. But if ultrasound can generate micromixing, thei
r energetic performances are still far lower than Rushton turbine ones. Thu
s the ultrasound technique must be used in a small zone to generate locally
a mixing on a small scale. Finally, the ultrasound technique was also test
ed in more visquous liquids (2-170 mPa s) and proved to be of great interes
t. (C) 1999 Elsevier Science Ltd. All rights reserved.