The convolution problem in COIN spectroscopy

Citation
J. Bok et al., The convolution problem in COIN spectroscopy, CHEM PHYS, 244(1), 1999, pp. 89-100
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS
ISSN journal
03010104 → ACNP
Volume
244
Issue
1
Year of publication
1999
Pages
89 - 100
Database
ISI
SICI code
0301-0104(19990601)244:1<89:TCPICS>2.0.ZU;2-V
Abstract
General formulae are derived for the interferometric COIN (Coherence Observ ation by Interference Noise) signal in the Limit of finite width pulses. Ga ussian and exponential forms of the pulses have been used in the numerical calculations of the COIN observable. Qualitative agreement with experiment is found for the form of the COIN signal. As compared to previous studies u sing the delta-function form of the pulses unexpected sensitivity of the ev aluated variance to the pulse-width, T-2-relaxation, and detuning is found. (C) 1999 Elsevier Science B.V. All rights reserved.